We don't see many skaters turn pro at a young age these days, but in the 1980s and 90s and may be a bit into the 21st century too, skaters had good careers as pros. Some did clearly better or worse than when they were eligible skaters.
The lists below are clearly incomplete because it's hard to list every skater that has retired/turned pro, but here is my best effort.
Group A: Some skaters have been much more successful as pros than they were as eligible skaters.
Group B: Some have been less successful (particularly when compared with their eligible accomplishments)
Group C: Successful in both eligible and pro careers
(I am primarily looking at the times when we had real 'pro' competitions, but other- non-competition- aspects can be considered too for skater that did not get to compete in the pro competitions).
Group A: (More successful as pros)
Yuka Sato
Caryn Kadavy
Surya Bonaly
Dan Hollander (he found his nitch- comedy)
Paul Wylie (he did win the Olympic silver, but he really blossomed as a pro)
Rudy Galindo
Bechke & Petrov
Underhill-Martini
Ina-Zimmerman
Punsalan-Swallow
Annenko & Sretenski
Rocca & Sur
Group B: (less successful as pros)
Oksana Baiul
Sarah Hughes
Tara Lipinski (injuries ended her career)
Maria Butyrskaya (actually, not sure where to put her)
Alexei Urmanov
Valova-Vassiliev
Mishkutenok-Dmitriev
Bestemianova-Bukin
Anissina-Peizerat
Selezneva-Makarov
Group C: (Successful in both)- it's tough to capture them all, because there were so many of them.
Brian Boitano
Brian Orser
Robin Cousins
Ilia Kulik (not many pro competitions though)
Kurt Browning
Viktor Petrenko (although I did not care for many of his pro routines)
Todd Eldredge (no pro competitions but he developed artistically)
Yagudin
Kristi Yamaguchi
Gordeeva-Grinkov
Sasha Cohen (no pro competitions but she was a great draw on tours)
Midori Ito
Debbie Thomas
Irina Slutskaya
Gordeeva-Grinkov
Kazakova-Dmitriev
Kitty & Peter Carruther
Klimova-Ponomarenko
Torville-Dean


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). But as professionals... wow. "Reverie" "The Man I Love" "Out of Tears" and especially, "Requiem"
Requiem is still one of the best professional routines ever skated. 
My faves are
For some reason, and I haven't seen the program in a while, I thought the Romeo & Juliet program had more transitions than a typical G&G eligible program? Maybe I loved the costumes & music so much I just convinced myself that they had transitions.
It would have
to imagine what kind of performances they would have been able to create if he had managed to stay in shape.
at U&Z performing to "Love Story." It's almost like a snarky inside joke. Not being familiar with the actual movie is ther a purpose to the balloon in the program? Or, is it just a prop?