Torvill and Dean. I still remember watching their programs.
Brian Orser was and is still a favourite, I could watch him do figures all day...gorgeous. My brother was lucky enough to share a changeroom with him at our first "big" competition and he coaches at the club where I skate. Tolled Cranston I remember watching a lot, also lucky enough to "hang" out with him in a previous life.
Dance (I didn't notice it until the 1976 Olympics): Pakhomova & Gorshov, Moiseeva & Minenkov, Regoeczy & Sallay, O'Conner & Millns, Torvill & Dean
Ladies: Carol Heiss, Peggy Fleming, Janet Lynn, Trixie Schuba
Men: David Jenkins, Donald Jackson, John Mischa Petkevich, Tim Wood, Scott E Allen,
Pairs (didn't really notice them till 1964): Protopopovs Kaufmans, Wagenhoffer & Heasley
Yes, a lot of these teams did not skate at exactly the same time.